Advances in Free-Radical Promoted C(sp<sup>3</sup>)—C(sp<sup>3</sup>) Bond Conversion
نویسندگان
چکیده
منابع مشابه
Free-radical carbon-carbon bond formation in organic synthesis.
Organic chemists have begun to use intra- and intermolecular free-radical addition reactions to develop useful synthetic transformations. Carboncentered radicals can form bonds with electron-rich or electron-deficient alkenes, allenes, and acetylenes. Radical addition reactions can also be used to construct hindered carbon-carbon bonds. These characteristics, as well as the large number of func...
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A photoinduced cascade strategy leading to a variety of differentially functionalised nitriles and ketones has been developed. These reactions rely on the oxidative generation of iminyl radicals from simple oximes. Radical transposition by C(sp3 )-(sp3 ) and C(sp3 )-H bond cleavage gives access to distal carbon radicals that undergo SH 2 functionalisations. These mild, visible-light-mediated pr...
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ژورنال
عنوان ژورنال: Chinese Journal of Organic Chemistry
سال: 2022
ISSN: ['0253-2786']
DOI: https://doi.org/10.6023/cjoc202108043